Correlation Analysis in Chemistry of Solutions (Hardback)
  • Correlation Analysis in Chemistry of Solutions (Hardback)
zoom

Correlation Analysis in Chemistry of Solutions (Hardback)

(author), (author), (author)
£260.00
Hardback 319 Pages / Published: 01/07/2004
  • We can order this

Usually dispatched within 3 weeks

  • This item has been added to your basket
The behavior of substances in solutions may not be adequately characterized by the effect of any single physicochemical parameter of solvents, nor are numerous semi-empirical scales of the solvent effect (their aEURO~polarityaEURO ™) suitable for their limited selections only. In recent decades, it has been found that the variation of reaction rate constants in solutions or that spectral parameters of dissolved substances are determined by the total effect of different solvation processes. This monograph presents numerous examples of such an approach and characterizes various empirical and semi-empirical scales of solvent properties. It is shown that additional consideration of some structural parameters of solvents, namely, their cohesive energy and the molar volume, may provide for spreading this approach on homolytical and catalytic reaction. It is also shown that for the solvolysis reaction, one of the excessive reagents may represent either a reagent or a solvent, which requires additional consideration of its structural characteristics in the Hammeth equation. The application of the principle of free energy linearity also allowed adequate generalization of data on the effect of solvents on different physicochemical processes, such as dissolution of gases and solids in various solvents, swelling of polymers and solid fossil fuels, coal extraction, adsorption, absorption, diffusion, and chromatography. Special attention is paid to substance distribution between two immiscible phases. Properties of both an extractive phase and an active extractant dissolved in inert diluter are taken into account. The majority of these processes indicate the efficiency of solvent self-association factor that defines the energy consumption for formation of a void for an alien molecule injection.

Publisher: Brill
ISBN: 9789067644068
Number of pages: 319
Weight: 658 g
Dimensions: 235 x 156 mm

You may also be interested in...

Renormalization Methods
Added to basket
Foundations of Physics for Chemists
Added to basket
Note-by-Note Cooking
Added to basket
£22.00
Hardback
Molecular Quantum Mechanics
Added to basket
An Introduction to Fire Dynamics
Added to basket
Statistical Mechanics
Added to basket
The Cosmic-Chemical Bond
Added to basket
Early Responses to the Periodic System
Added to basket
Why Chemical Reactions Happen
Added to basket
Radiation
Added to basket
£12.99
Paperback
Molecular Symmetry and Group Theory
Added to basket
Atkins' Molecules
Added to basket
£39.99
Paperback
Surfaces
Added to basket
£21.99
Paperback

Please sign in to write a review

Your review has been submitted successfully.