Comprehensive Organic Synthesis: Additions to and Substitutions at C-C-Pi-bonds v. 4: Selectivity, Strategy and Efficiency in Modern Organic Chemistry (Hardback)M. F. Semmelhack (volume editor)
Hardback Published: 08/09/1992
- Not available
Volume 4 focuses on additions and the resulting substitutions at carbon-carbon p-bonds. Part 1 includes processes generally considered as simple polar reactions, reactive electrophiles and nucleophiles adding to alkenes and alkynes. A major topic is Michael-type addition to electron deficient p-bonds, featured in the first six chapters. In part 2 are collected the four general processes leading to nucleophilic aromatic substitution, including radical chain processes and transition metal activation through to p-complexation. Metal-activated addition (generally by nucleophiles) to alkenes and polyenes is presented in part 3, including allylic alkylation catalyzed by palladium. The coverage of nonpolar additions in part 4 includes radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.
Publisher: Elsevier Science & Technology
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